Домашнее задание №1 по физической химии
Содержание домашнего задания
1. Рассчитать константу скорости заданной реакции k1 при данной температуре Т1 по заданным энергии активации Е и предэкспоненциальному множителю k0.
2. Найти зависимость между временем t и текущей концентрацией C и построить кинетическую кривую (график зависимости С от t); задать 6 - 10 равноотстоящих значений С и с помощью кинетического уравнения заданного порядка рассчитать соответствующие значения t.
3. Найти время полупревращения t1/2 аналитическим путем (по соответствующей формуле) и графическим путем (по графикам №1 и №2). Определить относительную ошибку определения.
4. Рассчитать, сколько % от исходной концентрации С0 первого вещества (то-есть написанного первым в уравнении реакции) (m1), и сколько кг этого вещества вступит в реакцию к заданному моменту времени t1 от начала опыта при заданной первоначально температуре T1 и заданном объеме V. Сколько кг продуктов образуется к этому времени? (Учесть, что в кинетические уравнения входит текущая, то-есть остающаяся концентрация вещества.
5. Найти температуру Т2, при которой за то же самое время t1 прореагирует m2% от С0. Объяснить, почему изменилась температура по сравнению с Т1.
6. Для первоначальной температуры Т1 построить график №2 зависимости от времени такой функции концентрации первого вещества, которая линейна относительно t. График должен быть построен во всем интервале концентраций. Из графика №2 определить графически константу скорости реакции k и время полупревращения t1/2.
7. Рассчитать, во сколько раз возрастет скорость реакции при температуре Т1 вследствие применения катализатора, снижающего энергию активации Е на n%.
Форма записи исходных данных
Реакция | поря-док | Т1,К | k0 | Е, Дж/моль | C0 моль/л | t1 с | V л | m2 % | n% |
Форма записи результатов
Константа скорости | Время полупревращения | Расход первого вещества к моменту t1 | к п.5 | ускорение при катализе | ||
k1 | графи-чески | аналити-чески | m1, % | кг | T2, K | kкат/k1 |
№ | Реакция | поря-док | Т1,К | k 0 | Е, Дж/моль | C0 моль/л | t1 с | V л | m2 % | n% | ||
1 | (CH3)2CO Þ CH4+CH2=CO | 1 | 831 | 8.1*1014 | 286330 | 0.3 | 100 | 1 | 15 | 1.5 | ||
2 | 2HI Þ H2+I2 | 2 | 558 | 9.2*1010 | 185800 | 0.01 | 1.5 107 | 150 | 1 | 16 | ||
3 | (CH3)2O Þ CH4 + HCHO | 1 | 710 | 2.4*1013 | 244530 | 0.5 | 200 | 10 | 20 | 2 | ||
4 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 570 | 1.0*1014 | 175560 | 5 | 80 | 90 | 30 | 25 | ||
5 | 2NO+Br2Þ 2NOBr | 3 | 283 | 27000 | 5434 | 0.0001 | 90000 | 950 | 17 | 16 | ||
6 | C2H5Br Þ C2H4 + HBr | 1 | 600 | 9*1013 | 217360 | 10 | 2000 | 10 | 45 | 3 | ||
7 | CH3ONO Þ CH3O. + NO. | 1 | 520 | 1.8 1013 | 152150 | 3 | 75 | 80 | 5 | 10 | ||
8 | (CH3CO)2O + C2H5OHÞ CH3COOC2H5+ CH3COOH | 2 | 303 | 9.13*104 | 51830 | 0.05 | 106 | 200 | 70 | 8 | ||
9 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 790 | 3.2*1011 | 227810 | 2.5 | 5*103 | 350 | 40 | 4.0 | ||
10 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 323 | 2.24*104 | 48822 | 0.2 | 4*104 | 100 | 25 | 5 | ||
11 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 303 | 105 | 66880 | 0.4 | 1*106 | 50 | 92 | 18 | ||
12 | 2NO+Br2Þ 2NOBr | 3 | 270 | 27000 | 5434 | 0.0001 | 85000 | 890 | 12 | 13 | ||
13 | N2O5ÞN2O4+0.5O2 | 1 | 275 | 4.9*1013 | 103288 | 0.9 | 8000 | 12 | 55 | 4 | ||
14 | CO2+OH-ÞHCO3- | 2 | 308 | 1.5*1010 | 37870 | 0.009 | 0.05 | 130 | 80 | 15 | ||
15 | (CH3)3CClÞ (CH3)2C=CH2+HCl | 1 | 570 | 2.5*1012 | 173052 | 10 | 9*103 | 90 | 2.0 | 20 | ||
16 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 700 | 1.0*1014 | 175560 | 0.2 | 6 | 70 | 45 | 20 | ||
17 | 2NO+Br2 Þ 2NOBr | 3 | 293 | 2.7*104 | 5434 | 0.0004 | 850 | 2000 | 29 | 28 | ||
18 | 2HI Þ H2+I2 | 2 | 620 | 9.2*1010 | 185800 | 0.03 | 1.8* 107 | 250 | 3 | 20 | ||
19 | CH3ONOÞ CH3O.+NO. | 1 | 520 | 1.8*1013 | 152150 | 1 | 85 | 100 | 2 | 25 | ||
20 | (CH3CO)2O +C2H5OH Þ CH3COOC2H5+ CH3COOH | 2 | 303 | 9.13*104 | 51832 | 0.005 | 106 | 200 | 70 | 8 | ||
21 | (CH3)2CO Þ CH4+CH2=CO | 1 | 831 | 8.1 1014 | 286330 | 1.0 | 70 | 6 | 40 | 4 | ||
22 | (CH3)3CBr Þ (CH3)2C=CH2 +HBr | 1 | 500 | 1.0*1014 | 175560 | 1 | 16000 | 100 | 30 | 25 | ||
23 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 790 | 3.2*1011 | 227810 | 1.5 | 5*103 | 350 | 60 | 14 | ||
24 | (CH3CO)2O +C2H5OH Þ CH3COOC2H5+ CH3COOH | 2 | 293 | 9.13*104 | 51832 | 0.05 | 4*105 | 300 | 80 | 5 | ||
25 | CH3ONO Þ CH3O.+NO. | 1 | 470 | 1.8*1013 | 152152 | 9 | 1500 | 20 | 40 | 4 | ||
26 | N2O5ÞN2O4+0.5O2 | 1 | 275 | 4.9*1013 | 103288 | 0.9 | 10000 | 2 | 60 | 3 | ||
27 | C2H5Br Þ C2H4 + HBr | 1 | 600 | 9*1013 | 217360 | 10 | 2000 | 10 | 45 | 3 | ||
28 | (CH3)3CBrÞ HBr +(CH3)2C=CH2+ | 1 | 530 | 1*1014 | 175560 | 9 | 9200 | 20 | 80 | 4 | ||
29 | (CH3CO)2O + C2H5OH Þ CH3COOC2H5+ CH3COOH | 2 | 275 | 9.13*104 | 51830 | 0.8 | 10000 | 1200 | 75 | 8 | ||
30 | CO2+OH-Þ HCO3- | 2 | 303 | 1.5*1010 | 87870 | 0.018 | 0.025 | 80 | 80 | 26 | ||
31 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 810 | 3.2*1011 | 227810 | 3.5 | 6*103 | 460 | 45 | 2.5 | ||
32 | CH3I+C6H5N(CH3)2Þ N(CH3)3+C6H5I | 2 | 318 | 2.24*104 | 48822 | 0.01 | 5*104 | 5 | 75 | 12 | ||
33 | CH3Br+I-ÞCH3I+Br- | 2 | 303 | 2.2*1010 | 76285 | 1 | 2000 | 500 | 20 | 25 | ||
34 | CH3ONOÞ CH3O.+NO. | 1 | 470 | 1.8 1013 | 152150 | 1 | 550 | 10 | 2 | 20 | ||
35 | (CH3)2O Þ CH4+HCHO | 1 | 750 | 2.4*1013 | 244530 | 0.45 | 1500 | 75 | 45 | 5.5 | ||
36 | 2NO+Br2Þ 2NOBr | 3 | 283 | 27000 | 5434 | 0.0001 | 80000 | 950 | 14 | 16 | ||
37 | (CH3)2CO Þ CH4+CH2=CO | 1 | 800 | 8.1*1014 | 286330 | 1.8 | 75 | 16 | 43 | 14 | ||
38 | CH3ONO Þ CH3O. + NO. | 1 | 510 | 1.8 1013 | 152150 | 1 | 85 | 20 | 4 | 25 | ||
39 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 400 | 105 | 66880 | 1.0 | 850000 | 40 | 83 | 10 | ||
40 | (CH3)3CClÞ (CH3)2C=CH2+HCl | 1 | 670 | 2.5*1012 | 173052 | 1.8 | 9 | 80 | 3 | 15 | ||
41 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 390 | 2.24*104 | 48822 | 0.8 | 500 | 90 | 28 | 15 | ||
42 | (CH3)2OÞ CH4+HCHO | 1 | 650 | 2.4*1013 | 244530 | 0.7 | 1*106 | 70 | 55 | 9 | ||
43 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 600 | 105 | 66880 | 2.0 | 7 | 65 | 43 | 10 | ||
44 | CO2+OH-ÞHCO3 | 2 | 308 | 1.5*1010 | 37870 | 0.01 | 0.06 | 150 | 85 | 20 | ||
45 | 2NO+Br2Þ 2NOBr | 3 | 283 | 27000 | 5434 | 0.001 | 60000 | 900 | 11 | 16 | ||
46 | CH3ONO Þ CH3O. + NO. | 1 | 495 | 1.8 1013 | 152150 | 2.7 | 700 | 75 | 6 | 12 | ||
47 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 390 | 2.24*104 | 48822 | 0.4 | 400 | 99 | 22 | 7 | ||
48 | N2O5Þ N2O4+0.5O2 | 1 | 275 | 4.9*1013 | 103288 | 0.6 | 8000 | 4 | 50 | 3 | ||
49 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 295 | 105 | 66880 | 0.8 | 8*106 | 45 | 87 | 12 | ||
50 | (CH3)3CCl Þ (CH3)2C=CH2+HCl | 1 | 590 | 2.5*1012 | 173052 | 8 | 950 | 78 | 3 | 14 | ||
51 | CO2+OH-Þ HCO3- | 2 | 323 | 1.5*1010 | 87870 | 0.19 | 0.1 | 78 | 66 | 20 | ||
52 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 800 | 3.2* 1011 | 227810 | 2.0 | 890 | 300 | 35 | 5 | ||
53 | C2H5Br Þ C2H4 + HBr | 1 | 590 | 9*1013 | 217360 | 8 | 120000 | 11 | 38 | 4 | ||
54 | CH3ONOÞ CH3O.+NO. | 1 | 520 | 490 | 152150 | 3.5 | 700 | 70 | 15 | 13 | ||
55 | 2HI Þ H2+I2 | 2 | 600 | 9.2 1010 | 185800 | 0.06 | 4*106 | 220 | 4 | 17 | ||
56 | (CH3CO)2O +C2H5OH Þ CH3COOC2H5 +CH3COOH | 2 | 323 | 9.13*104 | 51832 | 0.15 | 50000 | 150 | 66 | 9 | ||
57 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 810 | 3.2* 1011 | 227810 | 0.95 | 700 | 300 | 38 | 3 | ||
58 | CH3Br+I-Þ CH3I+Br- | 2 | 295 | 2.2*1010 | 76285 | 2 | 1800 | 450 | 18 | 22 | ||
59 | (CH3)2O Þ CH4 +HCHO | 1 | 710 | 2.4*1013 | 244530 | 0.9 | 110 | 73 | 38 | 7 | ||
60 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 290 | 105 | 66880 | 0.9 | 7*106 | 45 | 88 | 11 | ||
61 | (CH3CO)2O+ C2H5OH Þ CH3COOH +CH3COOC2H5 | 2 | 393 | 9.13 104 | 51830 | 0.09 | 900 | 190 | 55 | 7 | ||
62 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 400 | 2.24*104 | 48822 | 0.35 | 310 | 99 | 22 | 7 | ||
63 | 2HI Þ H2+I2 | 2 | 580 | 9.2 1010 | 185800 | 0.09 | 1.5 107 | 110 | 2 | 16 | ||
64 | CH3ONOÞ CH3O.+NO. | 1 | 550 | 1.8 1013 | 152150 | 7 | 40 | 18 | 220 | 5 | ||
65 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 550 | 1.0 1014 | 175560 | 6 | 7 00 | 80 | 22 | 20 | ||
66 | (CH3)3CClÞ (CH3)2C=CH2+HCl | 1 | 730 | 2.5*1012 | 173052 | 8.5 | 0.009 | 80 | 3 | 11 | ||
67 | CH3ONOÞ CH3O.+NO. | 1 | 390 | 1.8*1013 | 152152 | 6 | 780 | 22 | 30 | 7 | ||
68 | C2H5Br Þ C2H4 + HBr | 1 | 690 | 9*1013 | 217360 | 7.5 | 2*109 | 11 | 39 | 4 | ||
69 | CO2+OH-Þ HCO3- | 2 | 295 | 1.5*1010 | 87870 | 0.19 | 8*105 | 75 | 60 | 16 | ||
70 | (CH3)2COÞ CH4+HCHO | 1 | 710 | 2.4*1013 | 244530 | 0.9 | 760 | 70 | 40 | 8 | ||
71 | CH3ONOÞ CH3O.+NO. | 1 | 410 | 1.8*1013 | 152150 | 0.95 | 7*105 | 98 | 2.5 | 13 | ||
72 | CH3ONOÞ CH3O.+NO. | 1 | 600 | 1.8*1013 | 152150 | 0.9 | 0.6 | 70 | 6 | 10 | ||
73 | 2HI Þ H2+I2 | 2 | 610 | 9.2*1010 | 185800 | 0.02 | 3 107 | 220 | 4 | 11 | ||
74 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 420 | 105 | 66880 | 0.95 | 990000 | 44 | 60 | 11 | ||
75 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 500 | 1.0 1014 | 175560 | 2.5 | 7500 | 88 | 20 | 14 | ||
76 | CH3Br+I- ÞCH3I+Br- | 2 | 410 | 2.2*1010 | 76285 | 2.1 | 0.18 | 450 | 19 | 22 | ||
77 | (CH3)2CO Þ CH4+CH2=CO | 1 | 801 | 8.1*1014 | 286330 | 0.5 | 8000 | 330 | 45 | 8 | ||
78 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 295 | 2.24*104 | 48822 | 0,35 | 15000 | 90 | 12 | 7 | ||
79 | 2HI Þ H2+I2 | 2 | 556 | 9.2*1010 | 185800 | 0,01 | 1* 107 | 200 | 2 | 3 | ||
80 | CH3N=NCH3ÞC2H6+N2 | 1 | 550 | 9.8*1015 | 214016 | 9 | 18000 | 90 | 5 | 18 | ||
81 | (CH3CO)2O + C2H5OH Þ CH3COOH +CH3COOC2H5 | 2 | 335 | 9.13*104 | 51830 | 0.15 | 106 | 250 | 60 | 6 | ||
82 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 288 | 105 | 66880 | 0.2 | 7*107 | 2 | 25 | 20 | ||
83 | N2O5ÞN2O4+0.5O2 | 1 | 296 | 4.9*1013 | 103288 | 0.04 | 41000 | 650 | 9 | 30 | ||
84 | (CH3)2OÞ CH4+HCHO | 1 | 820 | 2.4*1013 | 244530 | 0.65 | 1200 | 170 | 70 | 8 | ||
85 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 740 | 3.2*1011 | 227810 | 4 | 90000 | 900 | 65 | 5 | ||
86 | CH3ONOÞ CH3O.+NO. | 1 | 460 | 1.8*1013 | 152150 | 6 | 3400 | 65 | 20 | 10 | ||
87 | 2NO+Br2Þ2NOBr | 3 | 305 | 27000 | 5434 | 0.0009 | 9000 | 1950 | 11 | 11 | ||
88 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 570 | 1.0*1014 | 175560 | 4 | 7900 | 98 | 40 | 35 | ||
89 | CH3ONO Þ CH3O.+NO. | 1 | 460 | 1.8*1013 | 152152 | 7 | 3000 | 50 | 25 | 10 | ||
90 | (CH3CO)2O +C2H5OH Þ CH3COOH +CH3COOC2H5 | 2 | 308 | 9.13*104 | 51832 | 0.7 | 5000 | 600 | 30 | 14 | ||
91 | 2HI Þ H2+I2 | 2 | 590 | 9.2 1010 | 185800 | 0.007 | 8*107 | 450 | 8 | 12 | ||
92 | (CH3)3CCl Þ (CH3)2C=CH2+HCl | 1 | 590 | 2.5*1012 | 173052 | 8 | 1500 | 30 | 73 | 8 | ||
93 | CO2+OH-Þ HCO3- | 2 | 308 | 1.5*1010 | 87870 | 0.005 | 0,08 | 277 | 10 | 20 | ||
94 | CH3N=NCH3 Þ C2H6+N2 | 1 | 580 | 9.8*1015 | 214016 | 3 | 6000 | 30 | 46 | 7 | ||
95 | CH3ONOÞ CH3O.+NO. | 1 | 490 | 1.8 1013 | 152150 | 8 | 3000 | 20 | 40 | 4 | ||
96 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 298 | 105 | 66880 | 0.005 | 1*109 | 4 | 89 | 26 | ||
97 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 760 | 3.2* 1011 | 227810 | 0.5 | 14500 | 100 | 15 | 2 | ||
98 | CH3Br+I-ÞCH3I+Br- | 2 | 286 | 2.2*1010 | 76285 | 0.2 | 1000 | 400 | 49 | 12 | ||
99 | (CH3)2O ÞCH4+HCHO | 1 | 730 | 2.4*1013 | 244530 | 0.2 | 750 | 55 | 43 | 4 | ||
100 | C2H5Br Þ C2H4 + HBr | 1 | 612 | 9*1013 | 217360 | 9 | 3800 | 25 | 44 | 2.5 | ||
101 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 323 | 2.24*104 | 48822 | 0.2 | 10000 | 298 | 10 | 24 | ||
102 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 500 | 1.0*1014 | 175560 | 3 | 140000 | 89 | 43 | 15 | ||
103 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 330 | 105 | 66880 | 0.6 | 3*105 | 249 | 87 | 13 | ||
104 | CH3N=NCH3 ÞC2H6+N2 | 1 | 580 | 9.8*1015 | 214016 | 8 | 2800 | 57 | 46 | 14 | ||
105 | 2HI Þ H2+I2 | 2 | 556 | 9.2*1010 | 185800 | 0.01 | 3*107 | 220 | 2 | 5 | ||
106 | N2O5 Þ N2O4+0.5O2 | 1 | 296 | 4.9*1013 | 103288 | 0.04 | 41000 | 290 | 6 | 30 | ||
107 | CH3ONOÞ CH3O.+NO. | 1 | 490 | 1.8*1013 | 152150 | 4 | 750 | 75 | 6 | 21 | ||
108 | CH3ONO Þ CH3O.+NO. | 1 | 460 | 1.8*1013 | 152152 | 4 | 9000 | 915 | 5 | 25 | ||
109 | 2NO+Br2Þ 2NOBr | 3 | 283 | 27000 | 5434 | 0.005 | 50 | 950 | 21 | 11 | ||
110 | CH3ONOÞ CH3O.+NO. | 1 | 510 | 1.8*1013 | 152150 | 2 | 200 | 90 | 5 | 15 | ||
111 | CH3Br+I-ÞCH3I+Br- | 2 | 315 | 2.2*1010 | 76285 | 0.05 | 1600 | 490 | 19 | 12 | ||
112 | (CH3)2OÞCH4+HCHO | 1 | 710 | 2.4*1013 | 244530 | 0.5 | 200 | 10 | 24 | 4 | ||
113 | (CH3CO)2O +C2H5OH Þ CH3COOH +CH3COOC2H5 | 2 | 333 | 9.13*104 | 51832 | 0.01 | 2*106 | 50 | 76 | 17 | ||
114 | CH3ONOÞ CH3O.+NO. | 1 | 480 | 1.8*1013 | 152150 | 9 | 3800 | 28 | 30 | 2 | ||
115 | CO2+OH- Þ HCO3- | 2 | 303 | 1.5*1010 | 87870 | 0.0005 | 2*108 | 25 | 94 | 20 | ||
116 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 500 | 1.0*1014 | 175560 | 4 | 17000 | 188 | 45 | 16 | ||
117 | CH3ONO Þ CH3O + NO | 1 | 475 | 1.8*1013 | 152150 | 9 | 3850 | 60 | 20 | 20 | ||
118 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 565 | 1.0*1014 | 175560 | 4 | 76 | 75 | 25 | 16 | ||
119 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 298 | 2.24*104 | 48822 | 0.05 | 750000 | 48 | 82 | 4 | ||
120 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 318 | 2.24*104 | 48822 | 0.01 | 50000 | 8 | 70 | 18 | ||
121 | (CH3)3CClÞ (CH3)2C=CH2+HCl | 1 | 570 | 2.5*1012 | 173052 | 1 | 27800 | 100 | 13 | 19 | ||
122 | (CH3)3COH Þ (CH3)2C=CH2+ H2O | 1 | 600 | 3.2*1011 | 227810 | 2,0 | 4000 | 330 | 35 | 3,5 | ||
123 | C2H5Br Þ C2H4 + HBr | 1 | 620 | 9*1013 | 217360 | 8 | 1500 | 11 | 44 | 4 | ||
124 | CH3N=NCH3ÞC2H6+N2 | 1 | 550 | 9.8*1015 | 214016 | 7,5 | 23000 | 88 | 4 | 16 | ||
125 | (CH3)2OÞCH4+HCHO | 1 | 695 | 2.4*1013 | 244530 | 0,3 | 890 | 70 | 40 | 4 | ||
126 | 2HI ÞH2+I2 | 2 | 570 | 9.2*1010 | 185800 | 0,02 | 1.5 107 | 200 | 2 | 11 | ||
127 | CH3ONOÞ CH3O.+NO. | 1 | 430 | 1.8*1013 | 152152 | 7 | 1*105 | 22 | 35 | 5 | ||
128 | CH3ONOÞ CH3O.+NO. | 1 | 500 | 1.8*1013 | 152150 | 4 | 700 | 77 | 6 | 11 | ||
129 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 280 | 105 | 66880 | 0,5 | 1.5*103 | 40 | 89 | 11 | ||
130 | (CH3CO)2O + C2H5OH Þ CH3COOH +CH3COOC2H5 | 2 | 330 | 9.13*104 | 51830 | 0,09 | 106 | 180 | 60 | 6 | ||
131 | CH3ONOÞ CH3O.+NO. | 1 | 495 | 1.8*1013 | 152150 | 1,2 | 770 | 99 | 3 | 20 | ||
132 | CH3Br+I-ÞCH3I+Br- | 2 | 265 | 2.2*1010 | 76285 | 0,95 | 1550 | 450 | 11 | 20 | ||
133 | CH3COOC2H5+OH-Þ CH3COO-+C2H5OH | 2 | 303 | 1.7*107 | 46858 | 0.5 | 20 | 150 | 86 | 22 | ||
134 | CH3Br+I- ÞCH3I +Br- | 2 | 303 | 2.3*1010 | 76285 | 1 | 2000 | 500 | 20 | 25 | ||
135 | (CH3)3COHÞ (CH3)2C=CH2+H2O | 1 | 710 | 3.2*1011 | 227810 | 4.5 | 70000 | 550 | 55 | 4 | ||
136 | (CH3)2OÞCH4+HCOH | 1 | 760 | 2.4*1013 | 244530 | 0.3 | 2000 | 65 | 55 | 7 | ||
137 | ClCOOCCl3Þ2COCl2 | 1 | 250 | 1.4*1013 | 60610 | 2 | 0.001 | 70 | 15 | 10 | ||
138 | 2NO+Br2Þ2NOBr | 3 | 283 | 27000 | 5434 | 0.0001 | 85000 | 950 | 17 | 15 | ||
139 | CH3COOC2H5+OH-Þ CH3COO-+C2H5OH | 2 | 333 | 1.7*107 | 46858 | 0.1 | 20 | 150 | 86 | 22 | ||
140 | (CH3)3CClÞ (CH3)2C=CH2+HCl | 1 | 630 | 2.5*1012 | 173052 | 3 | 240 | 80 | 20 | 11 | ||
141 | N2O5ÞN2O4+0.5O2 | 1 | 320 | 4.9*1013 | 103288 | 0.75 | 10000 | 2 | 60 | 3 | ||
142 | (CH3CO)2O +C2H5OH Þ CH3COOH+ CH3COOC2H5 | 2 | 313 | 9.13*104 | 51832 | 0,07 | 2*106 | 290 | 36 | 7 | ||
143 | CO2+OH-Þ HCO3- | 2 | 500 | 1.5*1010 | 87870 | 0,022 | 0.04 | 57 | 78 | 19 | ||
144 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 350 | 2.24*104 | 48822 | 0,16 | 30000 | 910 | 22 | 6 | ||
145 | (CH3)2OÞCH4+HCHO | 1 | 690 | 2.4*1013 | 244530 | 0.5 | 0.15 | 75 | 30 | 6 | ||
146 | 2HI Þ H2+I2 | 2 | 495 | 9.2 1010 | 185800 | 0,03 | 3*107 | 120 | 4 | 12 | ||
147 | CH3N=NCH3ÞC2H6+N2 | 1 | 480 | 9.8*1015 | 214016 | 6 | 16500 | 75 | 6 | 13 | ||
148 | 2NO+Br2Þ2NOBr | 3 | 280 | 27000 | 5434 | 0.0001 | 50000 | 950 | 11 | 16 | ||
149 | (CH3)3CClÞ (CH3)2C=CH2+HCl | 1 | 465 | 2.5*1012 | 173052 | 7 | 9*103 | 90 | 3 | 11 | ||
150 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 395 | 1.0 1014 | 175560 | 3 | 5700 | 88 | 20 | 14 | ||
151 | (CH3CO)2O+H2OÞ 2CH3COOH | 2 | 395 | 105 | 66880 | 0.1 | 2000 | 44 | 85 | 11 | ||
152 | CH3I +C6H5N(CH3)2 Þ N(CH3)3+C6H5I | 2 | 330 | 2.24*104 | 48822 | 0.35 | 4*104 | 99 | 20 | 4 | ||
153 | CH3ONO ÞCH3O.+NO. | 1 | 400 | 1.8*1013 | 152152 | 7 | 1500 | 11 | 20 | 6 | ||
154 | CH3N=NCH3ÞC2H6+N2 | 1 | 465 | 9.8*1015 | 214016 | 6 | 11000 | 88 | 7 | 14 | ||
155 | CO2+OH-Þ HCO3- | 2 | 395 | 1.5*1010 | 87870 | 0,025 | 0.02 | 77 | 80 | 18 | ||
156 | (CH3CO)2O +C2H5OH Þ CH3COOC2H5+ CH3COOH | 2 | 340 | 9.13*104 | 51832 | 0.05 | 106 | 120 | 80 | 9 | ||
157 | CO2+OH- Þ HCO3- | 2 | 270 | 1.5*1010 | 37871 | 0.005 | 0.3 | 200 | 70 | 11 | ||
158 | CH3Br+I- Þ CH3I+Br- | 2 | 275 | 2.2*1010 | 76285 | 0.9 | 4000 | 850 | 60 | 18 | ||
159 | C2H5Br Þ C2H4+HBr | 1 | 595 | 9.1*1013 | 217360 | 9 | 180000 | 10 | 40 | 4 | ||
160 | (CH3)2O Þ CH4+HCHO | 1 | 660 | 2.4*1013 | 244530 | 0.2 | 1100 | 75 | 35 | 7 | ||
161 | (CH3)3CCl Þ (CH3)2C=CH2+HCl | 1 | 550 | 2.5*1012 | 173052 | 5 | 9000 | 6 | 80 | 3 | ||
162 | CH3ONOÞ CH3O.+NO. | 1 | 440 | 1.8*1013 | 152152 | 5 | 1200 | 20 | 40 | 3 | ||
163 | 2HI Þ H2+I2 | 2 | 590 | 9.2*1010 | 185800 | 0.06 | 3*107 | 175 | 5 | 22 | ||
164 | CH3N=NCH3 Þ C2H6+N2 | 1 | 595 | 9.8*1015 | 214016 | 0.9 | 60000 | 15 | 65 | 3 | ||
165 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 600 | 1.0*1014 | 175560 | 1.2 | 650 | 100 | 36 | 21 | ||
166 | (CH3)2O Þ CH4+HCHO | 1 | 710 | 2.4*1013 | 244530 | 0.6 | 800 | 50 | 40 | 5 | ||
167 | (CH3)2CO Þ CH4+CH2CO | 1 | 800 | 8.1*1014 | 286330 | 0.8 | 70 | 7 | 30 | 5 | ||
168 | ClCOOCCl3Þ2COCl2 | 1 | 285 | 1.4*1013 | 60610 | 4 | 0.005 | 55 | 20 | 8 | ||
169 | CH3ONOÞ CH3O.+NO. | 1 | 510 | 1.8 1013 | 152150 | 0.3 | 840 | 850 | 13 | 6 | ||
170 | (CH3)3CBr Þ (CH3)2C=CH2+HBr | 1 | 585 | 1.0*1014 | 175560 | 5 | 7000 | 70 | 20 | 7 | ||
171 | (CH3)2O Þ CH4+HCHO | 1 | 775 | 2.4*1013 | 244530 | 0.5 | 1800 | 80 | 29 | 4 | ||
172 | 2NO+Br2Þ2NOBr | 3 | 255 | 27000 |
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